Dissertation/Thesis
IONIC FLUORINE CHEMISTRY.
| Τίτλος: | IONIC FLUORINE CHEMISTRY. |
|---|---|
| Συγγραφείς: | Hyde,Gene A., Trotz,Samuel I. |
| Συνεισφορές: | OLIN CORP NEW HAVEN CONN CHEMICALS GROUP |
| Πηγή: | DTIC AND NTIS |
| Έτος έκδοσης: | 1969 |
| Συλλογή: | Defense Technical Information Center: DTIC Technical Reports database |
| Θεματικοί όροι: | Inorganic Chemistry, (*FLUORIDES, SYNTHESIS(CHEMISTRY)), (*IODINE COMPOUNDS, COMPLEX COMPOUNDS), (*ANTIMONY COMPOUNDS, CESIUM COMPOUNDS, SALTS, INFRARED SPECTRA, X RAY DIFFRACTION, OXIDES, ANTIMONY HALOGEN COMPLEXES, CESIUM HALOGEN COMPLEXES, FLUORO MOLECULAR IONS, FLUOROMOLECULAR IONS, INTERHALOGEN COMPLEXES, IODO MOLECULAR IONS, IODOMOLECULAR IONS, ION MOLECULE CHEMISTRY, MOLECULAR IONS, OXYHALIDE IONS |
| Περιγραφή: | The report describes attempts to prepare iodine-fluorine interhalogen salts wherein both ions contain iodine and fluorine, or iodine, fluorine, and/or oxygen. Three starting materials were successfully prepared, CsIF6, IF4SbF6, and IF6SbF6, whose metathetical interactions would have given desired interhalogen salts. Failure to find suitable solvents for the intended reactions was primarily responsible for a lack of success in this area. In the course of preparing CsIF6 a previously unreported adduct was isolated, CsIF6.2IF5, and infrared and X-ray characteristics are given. One other positive aspect of the investigations is the partial clarification of the reactions of I2O5 with IF5 and IF7 as regards the synthesis of IO2F and 'IOF3'. (Author) |
| Τύπος εγγράφου: | Thesis |
| Περιγραφή αρχείου: | text/html |
| Γλώσσα: | English |
| Relation: | http://www.dtic.mil/docs/citations/AD0697970 |
| Διαθεσιμότητα: | http://www.dtic.mil/docs/citations/AD0697970 http://oai.dtic.mil/oai/oai?&verb=getRecord&metadataPrefix=html&identifier=AD0697970 |
| Rights: | APPROVED FOR PUBLIC RELEASE |
| Αριθμός Καταχώρησης: | edsbas.A4BC7C51 |
| Βάση Δεδομένων: | BASE |
| Η περιγραφή δεν είναι διαθέσιμη |