Academic Journal
Synthesis and characterisation of the new oxyanion doped “0201–1201” type layered oxide, Sr4.5Fe2(S/Cr)0.5O9±δ
| Title: | Synthesis and characterisation of the new oxyanion doped “0201–1201” type layered oxide, Sr4.5Fe2(S/Cr)0.5O9±δ |
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| Authors: | Jarvis, A., Berry, F. J., Marco, J.F., Cibin, G., Slater, P. R. |
| Contributors: | University of Birmingham, Engineering and Physical Sciences Research Council (UK), Science and Technology Facilities Council (UK), Diamond Light Source (UK), Ministerio de Ciencia e Innovación (España), Jarvis, A., #NODATA#, Consejo Superior de Investigaciones Científicas https://ror.org/02gfc7t72 |
| Publisher Information: | Elsevier |
| Publication Year: | 2024 |
| Collection: | Digital.CSIC (Consejo Superior de Investigaciones Científicas / Spanish National Research Council) |
| Description: | 7 pags., 7 figs., 4 tabs. ; This work reports on an oxyanion containing Sr–Fe–O perovskite-related layered oxide system related to the “0201–1201” type material Sr4.5Cr2.5O9. Using solid state synthesis, we successfully incorporate SO42− and CrO42− to give Sr4.5Fe2(S/Cr)0.5O9±δ, with X-ray and neutron diffraction used to analyse the structure of these materials. Neutron diffraction experiments combined with 57Fe Mössbauer spectroscopy and X-ray absorption spectroscopy show not only the successful oxyanion incorporation, but also that these systems have the ability to accommodate excess interstitial anions. The stabilisation of these new phases highlights the potential to synthesise new perovskite-related compounds using oxyanion doping. ; We would like to thank the University of Birmingham and EPSRC for funding (studentship for AJ). The authors also thank EPSRC for funding: the JUICED Hub (Joint University Industry Consortium for Energy (Materials) and Devices Hub), EP/R023662/1). We would like to thank the STFC ISIS Facility for the provision of neutron diffraction time, and Dr. A. Gibbs for help with data collection. We thank Diamond Light Source for the award of beam time as part of the Energy Materials Block Allocation Group. This work has been supported by Project No. TED2021-130957B–C54 funded by MCIN/AEI/10.13039/ 501100011033 and by the ‘‘European Union NextGenerationEU/ PRTR’’. ; Peer reviewed |
| Document Type: | article in journal/newspaper |
| Language: | English |
| ISBN: | 978-85-19-68052-4 85-19-68052-6 |
| Relation: | #PLACEHOLDER_PARENT_METADATA_VALUE#; info:eu-repo/grantAgreement/MICINN//TED2021-130957B–C54; Journal of Solid State Chemistry; https://doi.org/10.1016/j.jssc.2024.124822; Sí; Journal of Solid State Chemistry 338: 124822 (2024); https://hdl.handle.net/10261/364736; http://dx.doi.org/10.13039/100011889; http://dx.doi.org/10.13039/501100000266; http://dx.doi.org/10.13039/501100004837; http://dx.doi.org/10.13039/501100000271; http://dx.doi.org/10.13039/501100000855; https://api.elsevier.com/content/abstract/scopus_id/85196805267 |
| DOI: | 10.1016/j.jssc.2024.124822 |
| DOI: | 10.13039/100011889 |
| DOI: | 10.13039/501100000266 |
| DOI: | 10.13039/501100004837 |
| DOI: | 10.13039/501100000271 |
| DOI: | 10.13039/501100000855 |
| Availability: | https://hdl.handle.net/10261/364736 https://doi.org/10.1016/j.jssc.2024.124822 https://doi.org/10.13039/100011889 https://doi.org/10.13039/501100000266 https://doi.org/10.13039/501100004837 https://doi.org/10.13039/501100000271 https://doi.org/10.13039/501100000855 https://api.elsevier.com/content/abstract/scopus_id/85196805267 |
| Rights: | info:eu-repo/semantics/openAccess |
| Accession Number: | edsbas.92CF4CF4 |
| Database: | BASE |
| ISBN: | 9788519680524 8519680526 |
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| DOI: | 10.1016/j.jssc.2024.124822 |