Programmable DNA-mediated coordination polymer nanospheres as highly specific catechol oxidase mimics for biosensing and environmental monitoring.

Λεπτομέρειες βιβλιογραφικής εγγραφής
Τίτλος: Programmable DNA-mediated coordination polymer nanospheres as highly specific catechol oxidase mimics for biosensing and environmental monitoring.
Συγγραφείς: Xu W; College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao 266109, People's Republic of China. changjf@qau.edu.cn., Zhang J; College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao 266109, People's Republic of China. changjf@qau.edu.cn., Hou T; College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao 266109, People's Republic of China. changjf@qau.edu.cn., Li F; College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao 266109, People's Republic of China. changjf@qau.edu.cn., Chang J; College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao 266109, People's Republic of China. changjf@qau.edu.cn.
Πηγή: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2026 Oct 15; Vol. 62 (81), pp. 20437-20440. Date of Electronic Publication: 2026 Oct 15.
Τύπος έκδοσης: Journal Article
Γλώσσα: English
Στοιχεία περιοδικού: Publisher: Royal Society of Chemistry Country of Publication: England NLM ID: 9610838 Publication Model: Electronic Cited Medium: Internet ISSN: 1364-548X (Electronic) Linking ISSN: 13597345 NLM ISO Abbreviation: Chem Commun (Camb) Subsets: MEDLINE
Imprint Name(s): Original Publication: Cambridge : Royal Society of Chemistry
Ιατρικοί όροι (MeSH): Biosensing Techniques*/methods , Nanospheres*/chemistry , Catechol Oxidase*/chemistry , Catechol Oxidase*/metabolism , Polymers*/chemistry , Biomimetic Materials*/chemistry , DNA, Single-Stranded*/chemistry , DNA*/chemistry, Copper/chemistry
Περίληψη: We leverage adenine-rich single-stranded DNA as both a structural director and a coordination scaffold to synthesize Cu-coordination nanospheres. These nanospheres act as highly selective catechol oxidase mimics, exhibiting no peroxidase-like activity toward TMB or ABTS, thus overcoming the catalytic promiscuity inherent to conventional oxidase nanozymes.
Substance Nomenclature: EC 1.10.3.1 (Catechol Oxidase)
0 (Polymers)
789U1901C5 (Copper)
0 (DNA, Single-Stranded)
9007-49-2 (DNA)
Entry Date(s): Date Created: 20260924 Date Completed: 20261015 Latest Revision: 20261015
Update Code: 20261016
DOI: 10.1039/d6cc04881a
PMID: 42779311
Βάση Δεδομένων: MEDLINE
Περιγραφή
ISSN:1364-548X
DOI:10.1039/d6cc04881a