Academic Journal
Silver tungstate/magnesium oxide nanocomposite as a high-performance adsorbent for bromide removal from aqueous systems.
| Τίτλος: | Silver tungstate/magnesium oxide nanocomposite as a high-performance adsorbent for bromide removal from aqueous systems. |
|---|---|
| Συγγραφείς: | H A Aboterika A; Central Laboratory, Faculty of Science, Ain Shams University, Cairo 11566, Egypt., M A Shahlol O; Faculty of Petroleum Gas and Renewable Energy Engineering, Zawia University, Az-Zāwiyah, Libya., Kamel AH; Chemistry Department, College of Science, University of Bahrain, Sakhir 32038, Bahrain.; Chemistry Department, Faculty of Science, Ain Shams University, P.O. Box 11655, Cairo, Egypt E-mail: ahkamel76@sci.asu.edu.eg; ahmohamed@uob.edu.bh., A Ghabbour H; School of Health and Biomedical Sciences, RMIT University, Melbourne, Victoria 3083, Australia.; Department of Medicinal Chemistry, Faculty of Pharmacy, University of Mansoura, Mansoura 35516, Egypt., A Almehizia A; Drug Exploration and Development Chair (DEDC), Department of Pharmaceutical Chemistry, College of Pharmacy, King Saud University, P.O. Box 2457, Riyadh 11451, Saudi Arabia., M Naglah A; Drug Exploration and Development Chair (DEDC), Department of Pharmaceutical Chemistry, College of Pharmacy, King Saud University, P.O. Box 2457, Riyadh 11451, Saudi Arabia. |
| Πηγή: | Journal of water and health [J Water Health] 2026 Feb; Vol. 24 (2), pp. 189-203. Date of Electronic Publication: 2026 Jan 21. |
| Τύπος έκδοσης: | Journal Article |
| Γλώσσα: | English |
| Στοιχεία περιοδικού: | Publisher: IWA Pub Country of Publication: England NLM ID: 101185420 Publication Model: Print-Electronic Cited Medium: Print ISSN: 1477-8920 (Print) Linking ISSN: 14778920 NLM ISO Abbreviation: J Water Health Subsets: MEDLINE |
| Imprint Name(s): | Original Publication: London ; Avenel, NJ : IWA Pub., c2003- |
| Ιατρικοί όροι (MeSH): | Bromides*/chemistry , Water Pollutants, Chemical*/chemistry , Water Purification*/methods , Nanocomposites*/chemistry , Magnesium Oxide*/chemistry , Tungsten Compounds*/chemistry , Silver Compounds*/chemistry, Silver/chemistry ; Adsorption ; Kinetics ; X-Ray Diffraction |
| Περίληψη: | Bromide contamination in water sources poses significant health and environmental concerns due to its transformation into carcinogenic disinfection byproducts (DBPs) such as bromate during water treatment. In this study, a silver tungstate-modified magnesium oxide nanocomposite (Ag (© 2026 The Authors This is an Open Access article distributed under the terms of the Creative Commons Attribution Licence (CC BY 4.0), which permits copying, adaptation and redistribution, provided the original work is properly cited (http://creativecommons.org/licenses/by/4.0/).) |
| Competing Interests: | The authors declare there is no conflict. |
| References: | Abdel Hafez A. A., Abd-Rabboh H. S. M., Al-Marri A. M. & Aboterika A. H. A. (2023) Removal of toxic lead from wastewater by <i>Lupinus albus</i> seed hull, ACS Omega, 8, 42622–42631. doi:10.1021/acsomega.3c05337. (PMID: 38024686) Al-Ghouti M. A., Khan M., Malik A., Khraisheh M., Hijazi D., Mohamed S., Alsorour S., Eltayeb R., AlMahmoud F. & Alahmad J. (2022) Development of novel nano-<i>γ</i>-Al<sub>2</sub>O<sub>3</sub> adsorbent from waste aluminum foil for the removal of boron and bromide from aqueous solution, J. Water Process Eng., 50, 103312. doi:10.1016/j.jwpe.2022.103312. Amy G., Siddiqui M., Zhai W., DeBroux J. & Odem W. (1993) Nation-wide survey of bromide ion concentrations in drinking water sources. In <i>Proc. 1993 AWWA Ann. Conf., San Antonio, Texas</i>. Aouaini F., Knani S., Yahia M. B. & Lamine A. B. (2015) Statistical physics studies of multilayer adsorption isotherm in food materials and pore size distribution, Physica A, 432, 373–390. doi:10.1016/j.physa.2015.03.052. Arun S. B., Yatish K. V., Tigari G., Prashanth G. K., Lalithamba H. S. & Pramoda K. (2026) Bio-based plant-extract facilitated MgO nanocatalyst for the transformation of agriculture waste derived-feedstock into biodiesel and as nano-additive in diesel engine, Renew. Energy, 256 (Part D), 124218. doi:10.1016/j.renene.2025.124218. Bădescu S., Bulgariu D., Ahmad I. & Bulgariu L. (2018) Valorisation possibilities of exhausted biosorbents loaded with metal ions – a review, J. Environ. Manage., 224, 288–297. doi:10.1016/j.jenvman.2018.07.066. Balakrishnan G., Velavan R., Mujasam Batoo K. & Raslan E. H. (2020) Microstructure, optical and photocatalytic properties of MgO nanoparticles, Results Phys., 16, 103013. doi:10.1016/j.rinp.2020.103013. Dabhane H., Ghotekar S., Zate M., Kute S., Jadhav G. & Medhane V. (2022) Green synthesis of MgO nanoparticles using aqueous leaf extract of ajwain (<i>Trachyspermum ammi</i>) and evaluation of their catalytic and biological activities, Inorg. Chem. Commun., 138, 109270. Ding L., Deng H. P., Wu C. & Han X. (2012) Affecting factors, equilibrium, kinetics and thermodynamics of bromide removal from aqueous solutions by MIEX resin, Chem. Eng. J., 181, 360–370. doi:10.1016/j.cej.2011.11.096. Dorji P., Kim D. I., Hong S., Phuntsho S. & Shon H. K. (2020) Pilot-scale membrane capacitive deionisation for effective bromide removal and high water recovery in seawater desalination, Desalination, 479, 114309. doi:10.1016/j.desal.2020.114309. Elkatory M. R., Yılmaz M., Hassaan M. A. & El Nemr A. (2024) Fabrication of date palm kernel biochar-sulfur (DPKB-S) for super adsorption of methylene blue dye from water, Sci. Rep., 14, 6830. doi:10.1038/s41598-024-56939-w. (PMID: 38514691) ENSDW Egyptian Standards for Drinking and Domestic Uses (2007) Ministry of Health & Population, Ministerial Decree Number 458/2007, Egyptiangovnews, 290, Alamiria Presses. EU Directive Council (1998) On the quality of water intended for human consumption, Off. J. Eur. Commun., 330, 32–54. Gong C., Zhang Z., Qian Q., Liu D., Cheng Y. & Yuan G. (2013) Removal of bromide from water by adsorption on silver-loaded porous carbon spheres to prevent bromate formation, Chem. Eng. J., 218, 333–340. doi:10.1016/j.cej.2012.12.059. Gouveia A. F., Roca R. A., Macedo N. G., Cavalcante L. S., Longo E., San-Miguel M. A., Altomare A., da Silva G. S. & Andres J. (2022) Ag<sub>2</sub>WO<sub>4</sub> as a multifunctional material: Fundamentals and progress of an extraordinarily versatile semiconductor, J. Materials Research and Technology, 21, 4023–4051. doi.org/10.1016/j.jmrt.2022.11.011. Halder R. & Bandyopadhyay S. (2015) Synthesis and optical properties of anion deficient nano MgO, J. Alloy. Compd., 693, 534–542. doi:10.1016/j.jallcom.2016.09.164. Ho Y. S. (2006) Review of second-order models for adsorption systems, J. Hazard. Mater., 136, 681–689. doi:10.1016/j.jhazmat.2005.12.043. (PMID: 16460877) Hu J., Song Z., Chen L., Yang H., Li J. & Richards R. (2010) Adsorption properties of MgO(111) nanoplates for the dye pollutants from wastewater, J. Chem. Eng. Data, 55, 3742–3748. doi:10.1021/je100274e. Joshi R., Ratpukdi T., Knutson K., Bhatnagar A. & Khan E. (2022) Bromate formation control by enhanced ozonation: a critical review, Environ. Sci. Technol., 52, 1154–1198. Khan U. N., Inayat A., Shah G. M., Hassan H. M. A., Zaki M. E. A., Alanazi A. A., El-Zahhar A. A., Noureen S. & Abbas S. M. (2022) Green synthesis of magnesium oxide nanosheets by using <i>Citrullus colocynthis</i> fruit extract and its use in biofuel production, Biomass Bioenergy, 167, 106640. doi:10.1016/j.biombioe.2022.106640. Lagergren S. (1898) About the theory of so-called adsorption of soluble substances, K. Sven. Vetensk.akad. Handl., 24, 1–39. Langmuir I. (1918) The adsorption of gases on plane surfaces of glass, mica and platinum, J. Am. Chem. Soc., 40 (9), 1361–1403. doi:10.1021/ja02242a004. Liu S., Cheng G., Xiong Y., Ding Y. & Luo X. (2020) Adsorption of low concentrations of bromide ions from water by cellulose-based beads modified with TEMPO-mediated oxidation and Fe (III) complexation, J. Hazard. Mater., 384, 121195. doi:10.1016/j.jhazmat.2019.121195. (PMID: 31585281) Ma Y., Gu W., Shi C., Zhang X., Han L., Liu N., Luo T. & Zhang H. (2024) The performance and kinetics of flower-like MoS<sub>2</sub> for Hg<sup>2+</sup> removal from acidic wastewater, J. Ind. Eng. Chem., 132, 552–560. doi:10.1016/j.jiec.2023.11.050. Mohammed R. O., Amooey A. A., Ammar S. H. & Salman M. D. (2023) Enhanced photocatalytic degradation activity of ZIF-8 doped with Ag<sub>2</sub>WO<sub>4</sub> photocatalyst, J. Taiwan Inst. Chem. Eng., 151, 105141. doi:10.1016/j.jtice.2023.105141. Morrison C. M., Hogard S., Pearce R., Mohan A., Pisarenko A. N., Dickenson E. R. V., von Gunten U. & Wert E. C. (2023) Critical review on bromate formation during ozonation and control options for its minimization, Environ. Sci. Technol., 57, 18393–18409. doi:10.1021/acs.est.3c00538. (PMID: 37363871) Munagapati V. S. & Kim D.-S. (2016) Adsorption of anionic azo dye Congo red from aqueous solution by cationic modified orange peel powder, J. Mol. Liq., 220, 540–548. doi:10.1016/j.molliq.2016.04.119. Nariyan E., Aravindakshan N., Yu Q. J. & Li Q. (2020) Removal of iodides and bromides at parts per million concentrations using a novel bismuth composite material, Mater. Today Sustain., 10, 100054. Peng Q., Guo J., Zhang Q., Xiang J., Liu B., Zhou A., Liu R. & Tian Y. (2014) Unique lead adsorption behavior of activated hydroxyl group in two-dimensional titanium carbide, J. Am. Chem. Soc., 136, 4113–4116. doi:10.1021/ja500506k. (PMID: 24588686) Polo A. M. S., Velo-Gala I., Sánchez-Polo M., von Gunten U., López-Peñalver J. J. & Rivera-Utrilla J. (2016) Halide removal from aqueous solution by novel silver-polymeric materials, Sci. Total Environ., 573, 1125–1131. doi:10.1016/j.scitotenv.2016.08.071. (PMID: 27697745) Qiu X., Sasaki K., Osseo-Asare K., Hirajima T., Ideta K. & Miyawaki J. (2015) Sorption of H<sub>3</sub>BO<sub>3</sub>/B(OH)<sub>4</sub><sup>−</sup> on calcined LDHs including different divalent metals, J. Colloid Interface Sci., 445, 183–194. doi:10.1016/j.jcis.2014.12.093. (PMID: 25618238) Rajaeian B., Allard S., Joll C. & Heitz A. (2018) Effect of preconditioning on silver leaching and bromide removal properties of silver-impregnated activated carbon (SIAC), Water Res., 138, 152–159. (PMID: 29587151) Santos M. S., Alves A. & Madeira L. M. (2016) Chemical and photochemical degradation of polybrominated diphenyl ethers in liquid systems – a review, Water Res., 88, 39–59. doi:10.1016/j.watres.2015.09.044. (PMID: 26465809) Sharifpour E., Khafri H. Z., Ghaedi M., Asfaram A. & Jannesar R. (2018) Isotherms and kinetic study of ultrasound-assisted adsorption of malachite green and Pb<sup>2+</sup> ions from aqueous samples by copper sulfide nanorods loaded on activated carbon: experimental design optimization, Ultrason. Sonochem., 40, 373–382. doi:10.1016/j.ultsonch.2017.07.030. (PMID: 28946436) Song T., Gao F., Du X., Hao X. & Liu Z. (2023) Removal of boron in aqueous solution by magnesium oxide with the hydration process, Colloids Surf. A: Physicochem. Eng. Asp., 665, 131211. doi:10.1016/j.colsurfa.2023.131211. Thammannagowda V. K., Shivanna K. G. G., Parameshwarappa A. K., Hanumesh P. & Kalappa P. (2025) Photocatalytic degradation of methylene blue using CoFe<sub>2</sub>O<sub>4</sub>/Ag<sub>2</sub>WO<sub>4</sub>: efficiency in degradation of methylene blue dye removal and antimicrobial activity, Next Mater., 8, 100774. doi:10.1016/j.nxmate.2025.100774. Wang C., Wei Z., Wang L., Sun P. & Wang Z. (2015a) Assessment of bromide-based ionic liquid toxicity toward aquatic organisms and QSAR analysis, Ecotoxicol. Environ. Saf., 115, 112–118. doi:10.1016/j.ecoenv.2015.02.012. Wang X., Mao Y., Tang S., Yang H. & Xie Y. F. (2015b) Disinfection byproducts in drinking water and regulatory compliance: a critical review front, Environ. Sci. Eng., 9, 3–15. Wang Q., Liu X., Zhang M., Wang Z., Zhou Z. & Ren Z. (2019) Facile preparation of novel ion-imprinted polymers for selective extraction of Br(I) ions from aqueous solution, Ind. Eng. Chem. Res., 58 (16), 6670–6678. doi:10.1021/acs.iecr.8b06396. Wang T., Zhao H., Zhao X., Yang Q. & Liu D. (2020) Silver nanoparticles prepared by one step reaction via reducibility of a metal–organic framework to remove the toxic bromine ions, J. Chem. Eng. Data, 66 (1), 535–543. doi:10.1021/acs.jced.0c00774. Weber W. J. & Morris J. C. (1963) Kinetics of adsorption on carbon from solution, J. Sanit. Eng. Div., 89, 31–60. doi:10.1061/JSEDAI.0000430. Weinberg H. S., Krasner S. W., Richardson S. D. & Thruston A. D.Jr. (2002) The Occurrence of Disinfection By-Products (DBPs) of Health Concern in Drinking Water: Results of a Nationwide DBP Occurrence Study. Athens, GA: National Exposure Research Laboratory. WHO (2011) Guidelines for Drinking-Water Quality, 4th edn., Vol. 38, Geneva: WHO Chronicle, pp. 104–108. Wu H. & Qiu J. (2014) Adsorption performance for bromide ion using bromide ion–lanthanum nitrate modified chitosan imprinted polymer, Anal. Methods, 6 (6), 1890–1896. doi:10.1039/C3AY40687C. Yousefi M., Gholami M., Oskoei V., Mohammadi A. A., Baziar M. & Esrafili A. (2021) Comparison of LSSVM and RSM in simulating the removal of ciprofloxacin from aqueous solutions using magnetization of functionalized multi-walled carbon nanotubes: process optimization using GA and RSM techniques, J. Environ. Chem. Eng., 9, 105677. doi:10.1016/j.jece.2021.105677. |
| Grant Information: | ORF-RC-2025-0122 Female Center for Scientific and Medical Colleges, King Saud University |
| Contributed Indexing: | Keywords: Ag |
| Substance Nomenclature: | 0 (Bromides) 0 (Water Pollutants, Chemical) 3A3U0GI71G (Magnesium Oxide) 0 (Tungsten Compounds) SW0Y0WQ46I (tungstate) 3M4G523W1G (Silver) 0 (Silver Compounds) |
| Entry Date(s): | Date Created: 20260301 Date Completed: 20260709 Latest Revision: 20260709 |
| Update Code: | 20260711 |
| DOI: | 10.2166/wh.2026.187 |
| PMID: | 41764391 |
| Βάση Δεδομένων: | MEDLINE |
| ISSN: | 1477-8920 |
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| DOI: | 10.2166/wh.2026.187 |