Academic Journal

K-feldspar hygrochronology

Bibliographic Details
Title: K-feldspar hygrochronology
Authors: VILLA, IGOR MARIA, Hanchar, JM
Contributors: Villa, I, Hanchar, J
Publisher Information: Elsevier
US
Publication Year: 2013
Collection: Università degli Studi di Milano-Bicocca: BOA (Bicocca Open Archive)
Subject Terms: systematic analysi, alkali feldspar, swiss alp, geochronology, isotope, ar39-ar40, Settore GEOS-01/C - Geochimica e vulcanologia
Description: The significance of the multi-isotopic record preserved in K-feldspars is assessed on samples from the Aar metagranite, Central Alps, Switzerland having very tight independent geological constraints. Stepwise leaching reveals that two diachronically grown K-feldspar generations coexist: Kfs-1 (>= 35 Ma old, Ca-poor, Rb-Cl-rich, with low Sr-87/Sr-86 and high Pb-206/Pb-204) and Kfs-2 (<= 10 Ma old, antithetic isotopic signatures deriving from external fluids). Microtextures imaged by cathodoluminescence, backscattered electrons, and electron probe microanalysis are patchy and chemically heterogeneous, with pronounced enrichments in Ba in the retrogressed regions. This confirms the simultaneous presence of fluid-dominated retrogression and recrystallization and isotopic inheritance. The staircase-shaped Ar-40/Ar-39 age spectrum correlates with the Ca/K and Cl/K signatures. This reflects a mixture of heterochemical K-feldspar generations, and not an intracrystalline Ar gradient caused by diffusion. The shape of the age spectrum and the in vacuo release kinetics proceed from entirely different physical and geological phenomena. What K-feldspars can be effectively used for is to constrain the timing of the fluids that interacted with them by multi-isotopic analyses, rather than to model a "cooling history" from Ar-39 release alone. The identification of multiple mineral generations by imaging combined with multi-isotopic analysis enables the accurate dating of the events of a multistage evolution after the initial crystallization of the rock in which the minerals occur.
Document Type: article in journal/newspaper
File Description: STAMPA
Language: English
Relation: info:eu-repo/semantics/altIdentifier/wos/WOS:000312854900003; volume:101; firstpage:24; lastpage:33; numberofpages:10; journal:GEOCHIMICA ET COSMOCHIMICA ACTA; https://hdl.handle.net/10281/45140
DOI: 10.1016/j.gca.2012.09.047
Availability: https://hdl.handle.net/10281/45140
https://doi.org/10.1016/j.gca.2012.09.047
Accession Number: edsbas.C03E3D70
Database: BASE
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  – Url: https://hdl.handle.net/10281/45140#
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  Data: K-feldspar hygrochronology
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  Data: &lt;searchLink fieldCode=&quot;AR&quot; term=&quot;%22VILLA%2C+IGOR+MARIA%22&quot;&gt;VILLA, IGOR MARIA&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;AR&quot; term=&quot;%22Hanchar%2C+JM%22&quot;&gt;Hanchar, JM&lt;/searchLink&gt;
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  Data: Villa, I&lt;br /&gt;Hanchar, J
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  Data: Elsevier&lt;br /&gt;US
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  Data: 2013
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  Data: Universit&#224; degli Studi di Milano-Bicocca: BOA (Bicocca Open Archive)
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  Data: &lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22systematic+analysi%22&quot;&gt;systematic analysi&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22alkali+feldspar%22&quot;&gt;alkali feldspar&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22swiss+alp%22&quot;&gt;swiss alp&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22geochronology%22&quot;&gt;geochronology&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22isotope%22&quot;&gt;isotope&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22ar39-ar40%22&quot;&gt;ar39-ar40&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22Settore+GEOS-01%2FC+-+Geochimica+e+vulcanologia%22&quot;&gt;Settore GEOS-01/C - Geochimica e vulcanologia&lt;/searchLink&gt;
– Name: Abstract
  Label: Description
  Group: Ab
  Data: The significance of the multi-isotopic record preserved in K-feldspars is assessed on samples from the Aar metagranite, Central Alps, Switzerland having very tight independent geological constraints. Stepwise leaching reveals that two diachronically grown K-feldspar generations coexist: Kfs-1 (&gt;= 35 Ma old, Ca-poor, Rb-Cl-rich, with low Sr-87/Sr-86 and high Pb-206/Pb-204) and Kfs-2 (&lt;= 10 Ma old, antithetic isotopic signatures deriving from external fluids). Microtextures imaged by cathodoluminescence, backscattered electrons, and electron probe microanalysis are patchy and chemically heterogeneous, with pronounced enrichments in Ba in the retrogressed regions. This confirms the simultaneous presence of fluid-dominated retrogression and recrystallization and isotopic inheritance. The staircase-shaped Ar-40/Ar-39 age spectrum correlates with the Ca/K and Cl/K signatures. This reflects a mixture of heterochemical K-feldspar generations, and not an intracrystalline Ar gradient caused by diffusion. The shape of the age spectrum and the in vacuo release kinetics proceed from entirely different physical and geological phenomena. What K-feldspars can be effectively used for is to constrain the timing of the fluids that interacted with them by multi-isotopic analyses, rather than to model a &quot;cooling history&quot; from Ar-39 release alone. The identification of multiple mineral generations by imaging combined with multi-isotopic analysis enables the accurate dating of the events of a multistage evolution after the initial crystallization of the rock in which the minerals occur.
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  Data: 10.1016/j.gca.2012.09.047
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  Data: https://hdl.handle.net/10281/45140&lt;br /&gt;https://doi.org/10.1016/j.gca.2012.09.047
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      – SubjectFull: alkali feldspar
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