Academic Journal
Crystal structures and photophysical properties of mono- and dinuclear ZnII complexes flanked by triethylammonium
| Τίτλος: | Crystal structures and photophysical properties of mono- and dinuclear ZnII complexes flanked by triethylammonium |
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| Συγγραφείς: | Hai, Le Thi Hong, Hien, Nguyen, Duong, Trinh Hong, Ninh, Nguyen Hoang, Khanh, Nguyen Nhat, Van Meervelt, Luc |
| Πηγή: | Acta Crystallogr E Crystallogr Commun Acta Crystallographica Section E: Crystallographic Communications, Vol 80, Iss 11, Pp 1210-1216 (2024) |
| Στοιχεία εκδότη: | International Union of Crystallography (IUCr), 2024. |
| Έτος έκδοσης: | 2024 |
| Θεματικοί όροι: | crystal structure, Science & Technology, Crystallography, OLEDS, 8-hydroxyquinoline derivatives, Zn(II) complex, zn(ii) complex, 34 Chemical sciences, SCHIFF-BASE, schiff base, Research Communications, ZN(II) COMPLEXES, Schiff base, BLUE, QD901-999, Physical Sciences, 8-HYDROXYQUINOLINE, 8-hydroxyquinoline derivatives, ZINC-COMPLEXES |
| Περιγραφή: | Two new zinc(II) complexes, triethylammonium dichlorido[2-(4-nitrophenyl)-4-phenylquinolin-8-olato]zinc(II), (C6H16N){Zn(C21H13N2O3)Cl2] (ZnOQ), and bis(triethylammonium) {2,2′-[1,4-phenylenebis(nitrilomethylidyne)]diphenolato}bis[dichloridozinc(II)], (C6H16N)2[Zn2(C20H14N2O2)Cl4] (ZnBS), were synthesized and their structures were determined using ESI–MS spectrometry, 1H NMR spectroscopy, and single-crystal X-ray diffraction. The results showed that the ligands 2-(4-nitrophenyl)-4-phenylquinolin-8-ol (HOQ) and N,N′-bis(2-hydroxybenzylidene)benzene-1,4-diamine (H2BS) were deprotonated by triethyl-amine, forming the counter-ion Et3NH+, which interacts via an N—H...O hydrogen bond with the ligand. The ZnII atoms have a distorted trigonal–pyramidal (ZnOQ) and distorted tetrahedral (ZnBS) geometries with a coordination number of four, coordinating with the ligands via N and O atoms. The N atoms coordinating with ZnII correspond to the heterocyclic nitrogen for the HOQ ligand, while for the H2BS ligand, it is the nitrogen of the imine (CH=N). The crystal packing of ZnOQ is characterized by C—H...π interactions, while that of ZnBS by C—H...Cl interactions. The emission spectra showed that ZnBS complex exhibits green fluorescence in the solid state with a small band-gap energy, and the ZnOQ complex does exhibit non-fluorescence. |
| Τύπος εγγράφου: | Article Other literature type |
| ISSN: | 2056-9890 |
| DOI: | 10.1107/s2056989024010302 |
| Σύνδεσμος πρόσβασης: | https://pubmed.ncbi.nlm.nih.gov/39712172 https://doaj.org/article/8876af9deadb41cfb43591ab59d5a438 https://lirias.kuleuven.be/handle/20.500.12942/759573 https://doi.org/10.1107/s2056989024010302 |
| Rights: | CC BY URL: http://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| Αριθμός Καταχώρησης: | edsair.doi.dedup.....582bcad7a8b53ad448b226d7fa66829a |
| Βάση Δεδομένων: | OpenAIRE |
| ISSN: | 20569890 |
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| DOI: | 10.1107/s2056989024010302 |