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Stirring chemical reaction landscapes through strong light–matter interactions.

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Τίτλος: Stirring chemical reaction landscapes through strong light–matter interactions.
Συγγραφείς: Singh, Jaibir, Garg, Pallavi, Lather, Jyoti, George, Jino
Πηγή: Chemical Communications; 12/4/2025, Vol. 61 Issue 93, p18289-18301, 13p
Θεματικοί όροι: Light matter interaction (Quantum optics), Chemical reactions, Polarity (Chemistry), Spectrum analysis instruments, Chemical kinetics, Molecular switches, Chemical relaxation
Περίληψη: Recent experiments suggest that precise control of chemical reactions can now be achieved by strong light–matter coupling. This fueled a huge interest among researchers to use it as a spectroscopic tool to understand complex chemical relaxation pathways. In this review, we show the potential of polaritonic chemistry that can be used as a selective tool without using any external stimuli. Polariton-driven reactions are proposed based on photoswitches, all the way up to simple ester hydrolysis, that are otherwise mediated by light or thermal sources. We also discuss the cooperativity and collective nature of strong coupling that can tailor reaction rates by inter-/intramolecular interactions. Furthermore, we explain the pros and cons of this concept, its potential to be explored in different domains, and the challenges upfront. [ABSTRACT FROM AUTHOR]
Copyright of Chemical Communications is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Stirring chemical reaction landscapes through strong light–matter interactions.
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  Data: <searchLink fieldCode="AR" term="%22Singh%2C+Jaibir%22">Singh, Jaibir</searchLink><br /><searchLink fieldCode="AR" term="%22Garg%2C+Pallavi%22">Garg, Pallavi</searchLink><br /><searchLink fieldCode="AR" term="%22Lather%2C+Jyoti%22">Lather, Jyoti</searchLink><br /><searchLink fieldCode="AR" term="%22George%2C+Jino%22">George, Jino</searchLink>
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  Data: Chemical Communications; 12/4/2025, Vol. 61 Issue 93, p18289-18301, 13p
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  Data: <searchLink fieldCode="DE" term="%22Light+matter+interaction+%28Quantum+optics%29%22">Light matter interaction (Quantum optics)</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+reactions%22">Chemical reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Polarity+%28Chemistry%29%22">Polarity (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Spectrum+analysis+instruments%22">Spectrum analysis instruments</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+kinetics%22">Chemical kinetics</searchLink><br /><searchLink fieldCode="DE" term="%22Molecular+switches%22">Molecular switches</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+relaxation%22">Chemical relaxation</searchLink>
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  Label: Abstract
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  Data: Recent experiments suggest that precise control of chemical reactions can now be achieved by strong light–matter coupling. This fueled a huge interest among researchers to use it as a spectroscopic tool to understand complex chemical relaxation pathways. In this review, we show the potential of polaritonic chemistry that can be used as a selective tool without using any external stimuli. Polariton-driven reactions are proposed based on photoswitches, all the way up to simple ester hydrolysis, that are otherwise mediated by light or thermal sources. We also discuss the cooperativity and collective nature of strong coupling that can tailor reaction rates by inter-/intramolecular interactions. Furthermore, we explain the pros and cons of this concept, its potential to be explored in different domains, and the challenges upfront. [ABSTRACT FROM AUTHOR]
– Name: Abstract
  Label:
  Group: Ab
  Data: <i>Copyright of Chemical Communications is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1039/d5cc04712a
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        Text: English
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      – SubjectFull: Chemical reactions
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      – SubjectFull: Polarity (Chemistry)
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      – SubjectFull: Spectrum analysis instruments
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      – SubjectFull: Chemical kinetics
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      – SubjectFull: Molecular switches
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            – D: 04
              M: 12
              Text: 12/4/2025
              Type: published
              Y: 2025
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