Academic Journal

Tunable dislocations overcome mechano-functional tradeoff in perovskite oxides.

Bibliographic Details
Title: Tunable dislocations overcome mechano-functional tradeoff in perovskite oxides.
Authors: Zhang, Jiawen1, Lu, Wenjun1 luwj@sustech.edu.cn, Fang, Xufei2 xufei.fang@kit.edu
Source: Science Advances. 8/7/2026, Vol. 12 Issue 32, p1-10. 10p.
Subject Terms: *Mechanical behavior of materials, *Material plasticity, *Thermal conductivity, *Ceramics, *Ceramic engineering, *Oxide ceramics, *Dislocation structure
Abstract: Recent advancements in dislocation engineering are reshaping the traditional view towards ceramics being brittle. Here, we use KTaO3 (KTO), a perovskite oxide that is newly discovered with room-temperature bulk plasticity, and demonstrate that the seeded dislocations can effectively tune both mechanical and functional properties. We uncover a brittle-ductile-brittle (BDB) transition: low dislocation densities lead to brittle failure, intermediate densities (~1014 m-2) enable superior compression plastic deformation capacity with strains over 20%, and high dislocation densities (~1015 m-2) induce brittle fracture again. This dislocation density-dependent non-monotonic mechanical response challenges the traditional behavior of ceramics and offers design opportunities. Furthermore, dislocation densities can monotonically decrease thermal conductivity, revealing a tradeoff between mechanical strength and functionality. The findings reveal a critical threshold of dislocation density in optimizing the performance of functional oxides, and provide a framework for using dislocations to design advanced materials where mechanical durability and enhanced functionality are intertwined. [ABSTRACT FROM AUTHOR]
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  Data: Tunable dislocations overcome mechano-functional tradeoff in perovskite oxides.
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  Data: <searchLink fieldCode="AR" term="%22Zhang%2C+Jiawen%22">Zhang, Jiawen</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Lu%2C+Wenjun%22">Lu, Wenjun</searchLink><relatesTo>1</relatesTo><i> luwj@sustech.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Fang%2C+Xufei%22">Fang, Xufei</searchLink><relatesTo>2</relatesTo><i> xufei.fang@kit.edu</i>
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  Data: <searchLink fieldCode="JN" term="%22Science+Advances%22">Science Advances</searchLink>. 8/7/2026, Vol. 12 Issue 32, p1-10. 10p.
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  Data: *<searchLink fieldCode="DE" term="%22Mechanical+behavior+of+materials%22">Mechanical behavior of materials</searchLink><br />*<searchLink fieldCode="DE" term="%22Material+plasticity%22">Material plasticity</searchLink><br />*<searchLink fieldCode="DE" term="%22Thermal+conductivity%22">Thermal conductivity</searchLink><br />*<searchLink fieldCode="DE" term="%22Ceramics%22">Ceramics</searchLink><br />*<searchLink fieldCode="DE" term="%22Ceramic+engineering%22">Ceramic engineering</searchLink><br />*<searchLink fieldCode="DE" term="%22Oxide+ceramics%22">Oxide ceramics</searchLink><br />*<searchLink fieldCode="DE" term="%22Dislocation+structure%22">Dislocation structure</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: Recent advancements in dislocation engineering are reshaping the traditional view towards ceramics being brittle. Here, we use KTaO3 (KTO), a perovskite oxide that is newly discovered with room-temperature bulk plasticity, and demonstrate that the seeded dislocations can effectively tune both mechanical and functional properties. We uncover a brittle-ductile-brittle (BDB) transition: low dislocation densities lead to brittle failure, intermediate densities (~1014 m-2) enable superior compression plastic deformation capacity with strains over 20%, and high dislocation densities (~1015 m-2) induce brittle fracture again. This dislocation density-dependent non-monotonic mechanical response challenges the traditional behavior of ceramics and offers design opportunities. Furthermore, dislocation densities can monotonically decrease thermal conductivity, revealing a tradeoff between mechanical strength and functionality. The findings reveal a critical threshold of dislocation density in optimizing the performance of functional oxides, and provide a framework for using dislocations to design advanced materials where mechanical durability and enhanced functionality are intertwined. [ABSTRACT FROM AUTHOR]
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      – Type: doi
        Value: 10.1126/sciadv.aed0057
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        Text: English
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      – SubjectFull: Mechanical behavior of materials
        Type: general
      – SubjectFull: Material plasticity
        Type: general
      – SubjectFull: Thermal conductivity
        Type: general
      – SubjectFull: Ceramics
        Type: general
      – SubjectFull: Ceramic engineering
        Type: general
      – SubjectFull: Oxide ceramics
        Type: general
      – SubjectFull: Dislocation structure
        Type: general
    Titles:
      – TitleFull: Tunable dislocations overcome mechano-functional tradeoff in perovskite oxides.
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            NameFull: Zhang, Jiawen
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            NameFull: Lu, Wenjun
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            NameFull: Fang, Xufei
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            – D: 07
              M: 08
              Text: 8/7/2026
              Type: published
              Y: 2026
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              Value: 32
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